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Crystal and molecular structure of aquabis(2,2′-bipyridine)nitratomanganese(II) nitrate monohydrate

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Abstract

A new monomeric manganese(II) nitrate complex with 2,2′-bipyridine (bpy), [Mn(bpy)2(NO3)(H2O)](NO3)·H2O, has been prepared and characterized by X-ray crystallography. The complex crystallizes in the triclinic space group\(P\bar 1\) witha=9.721(3),b=14.691(5),c=8.578(3) Å, α=106.79(3), β=96.05(3), γ=82.55(3)°,V=1159.9 Å3 andZ=2. The structure comprises discrete cation [Mn(bpy)2(NO3)(H2O)]+ in which the metal atom is coordinated by a pair of bidentate bpy ligands [Mn−N=2.261(4)−2.299(4) Å], a unidentate nitrato [Mn−O=2.284(4) Å] and aqua [Mn−O=2.160(3) Å] ligands in a highly distorted octahedral arrangement.

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Authors and Affiliations

  1. Department of Chemistry, Zhongshan University, 135 Xingang Rd. W., 510275, Guangzhou, China

    Xiao-Ming Chen & Yong-Jia Zhu

  2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002, Fuzhou, Fujian, China

    Xiao-Ying Huang & Yong-Jin Xu

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  1. Xiao-Ming Chen
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  2. Xiao-Ying Huang
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  3. Yong-Jin Xu
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  4. Yong-Jia Zhu
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Chen, XM., Huang, XY., Xu, YJ. et al. Crystal and molecular structure of aquabis(2,2′-bipyridine)nitratomanganese(II) nitrate monohydrate. J Chem Crystallogr 25, 605–607 (1995). https://doi.org/10.1007/BF01667032

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  • DOI: https://doi.org/10.1007/BF01667032

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