Abstract
The structure consists of two acetyl-substituted PCU cages linked by a diyne fragment. The conformation about the linker is midway between staggered and eclipsed, and the acetyl groups are somewhat distorted due to the proximity to the bulky cage units.
Similar content being viewed by others
References
Marchand, A. P. InAdvances in Theoretically Interesting Molecules; Thummel, R. P., Ed.; JAI Press: Greenwich, CT; 1989, Vol. 1. pp 357–399;
Marchand, A. P.Synlett 1991,73.
Marchand, A. P.; Rajagopal, D.; Burritt, A.; Bott, S. G.; Watson, W. H.; Sun, D. Manuscript in preparation.
For a review of Cu(I) promoted oxidative dimerization of terminal acetylenes, see: Eglinton, G.; McGraw, W.Advances in Organic Chemistry 1963,4, 252–274.
Mason, M. R.; Smith, J. M.; Bott, S. G.; Barron, A. R.J. Am. Chem. Soc. 1993,115, 4971.
Burla, M. C.; Camalli, M.; Cascarano, G.; Giacovazzo, C.; Polidori, G.; Spagna, R.; Viterbo, D.J. Appl. Crystallogr. 1989,22, 389.
Enraf-Nonius.MolEN, An Interactive Structure Solution Procedure. Enraf-Nonius: Delft, The Netherlands. 1990.
International Tables for X-ray Crystallography, Vol. IV; Kynoch Press: Birmingham, UK, 1974; pp 99, 149.
Johnson, C. K.ORTEPII Report ORNL-5138, 1976, Oak Ridge National Laboratory: TN.
Allen, F. H.; Kennard, O.; Watson, D. G.; Brammer, L.; Orpen, A. G.; Taylor, R.J. Chem. Soc., Perkin Trans. II 1987,S1.
Fukawa, K.; Harada, S.; Kasai, N.; Toda, F.; Mori, K.; Toda, F.Bull. Chem. Soc. Jpn. 1989,62, 2714.
Moorthy, J. N.; Venkatesan, K.J. Org. Chem. 1991,56, 6957. For some examples in which the O-groups aresyn, see Kaftory, M.; Yagi, M.; Tanaka, K.; Toda, F.J. Org. Chem. 1988,53, 4391.
Bott, S. G.; Marchand, A. P.; Liu, Z.J. Chem. Crystallogr., in press, 1995.
Ōsawa, E.; Kanematsu, K.Molecular Structure and Energetics, Vol. 3; Liebman, J. F.; Greenberg, A. (Eds.); VCH: New York; 1986, pp 329–369
Marchand, A. P.; Huang, C.; Kaya, R.; Baker, A. D.; Jemmis, E. D.; Dixon, D. A.,J. Am. Chem. Soc. 1987,107, 7095.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Bott, S.G., Marchand, A.P., Talafuse, L.K. et al. Structure of the product formed via Cu(I)-promoted oxidative dimerization ofexo-8-ethynylpentacyclo[5.4.0.02,6.03,10.05.9]undecan-endo-8-ol. J Chem Crystallogr 25, 543–547 (1995). https://doi.org/10.1007/BF01667022
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01667022