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Structure of the product formed via Cu(I)-promoted oxidative dimerization ofexo-8-ethynylpentacyclo[5.4.0.02,6.03,10.05.9]undecan-endo-8-ol

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Abstract

The structure consists of two acetyl-substituted PCU cages linked by a diyne fragment. The conformation about the linker is midway between staggered and eclipsed, and the acetyl groups are somewhat distorted due to the proximity to the bulky cage units.

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Bott, S.G., Marchand, A.P., Talafuse, L.K. et al. Structure of the product formed via Cu(I)-promoted oxidative dimerization ofexo-8-ethynylpentacyclo[5.4.0.02,6.03,10.05.9]undecan-endo-8-ol. J Chem Crystallogr 25, 543–547 (1995). https://doi.org/10.1007/BF01667022

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  • DOI: https://doi.org/10.1007/BF01667022

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