Abstract
The synthesis and crystal structure of 1,4-S,S′-isothiosemicarbazidebutane dihydrobromide have been presented. The crystals are monoclinic:P21/n, a=7.9910(10),b=10.979(2),c=8.9240(10)Å, β=111.450(10)°,Z=2, room temp. The structure was solved by direct methods. and refined to R=0.0297 for 846 reflections. The title compound consists of the centrosymmetric [C6H18N6S2]2+ dication and two Br− anions. Intramolecular N−H...N and intermolecular N−H...Br hydrogen bonds stabilizetrans conformation of the thiosemicarbazide moiety.
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Ciunik, Z., Drabent, K. & Rudolf, M.F. Crystal and molecular structure of 1,4-S,S′-bis-isothiosemicarbazidebutane dihydrobromide. J Chem Crystallogr 24, 507–510 (1994). https://doi.org/10.1007/BF01666728
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DOI: https://doi.org/10.1007/BF01666728