Abstract
The structure of the title compound, DTMP (C15H17NS2O), has been investigated in solution and in the solid state by IR, NMR and X-ray methods. The crystal structure was solved by direct methods and refined by least-squares procedures to anR-factor of 0.073. The piperidine ring adopts achair conformation. The methyl and thioenyl rings are in theequatorial position. The angle between the best plane of the piperidine ring and the thioenyl rings A and B are 88.1(1)° and 89.5(1)°, respectively.
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Ferguson, L.N.Chem. Soc. Rev. 1975,4, 289.
Loeppky, R.N.; Tomasik, W.; Kerride, B.E.Carcinogenesis 1987,8, 941.
Sapse, A.M.; Allen, E.B.; Lown, J.W.J. Am. Chem. Soc. 1988,110, 5671.
Magee, P.N.; Barnes, J.M.Cancer Res. 1967,10, 163.
Ravindran, T.; Jeyaraman, R.; Murray, R.W.; Singh, M.J. Org. Chem. 1991,10, 163.
Roques, R.; Declercq, J.P.; Germain, G.; Graffin, P.; Kamenka, J.M.; Geneste, P.Acta Cryst. 1981,B37, 712.
De camp, W.H.; Micovic, I.V.; Pelletier, S.W.Cryst. Struct. Commun. 1974,3, 427.
Sukumar, N.; Ponnuswamy, M.N.; Thenmozhiyal, J.C.; Jeyaraman, R.J. Cryst. Spec. Res. 1993,23, 871.
Sukumar, N.; Ponnuswamy, M. N.; Thenmozhiyal, J.C.; Jeyaraman, R.Bull. Chem. Soc. Jpn. 1994,67, 1069.
Allen, F.H.; Kennard, O.; Watson, D.G.; Brammer, L.; Orpen, A.G.; Taylor, R.J. Chem. Soc. Perkin Trans II,1987,S1.
Nardelli, M.Comput. Chem. 1983,7, 95.
Motherwell, W.D.S.; Clegg, W.PLUTO: Program for plotting molecular and crystal structures; University of Cambridge: England, 1978.
Sheldrick, G.M.Acta Cryst. 1990,A46, 467.
Sheldrick, G.M.SHELX76: Program for crystal structure determination; University of Cambridge: England, 1976.
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Sukumar, N., Ponnuswamy, M.N., Thenmozhiyal, J.C. et al. Structural characterization of 2,6-di(2-thioenyl)-3,5-dimethyl piperidin-4-one (DTMP) in solution and solid state. J Chem Crystallogr 25, 177–179 (1995). https://doi.org/10.1007/BF01666103
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DOI: https://doi.org/10.1007/BF01666103