Abstract
The title compound I (C10H7NS2) is orthorhombic: Pbca,a=16.223(6),b=15.065(5),c=7.356(4) Å. The conformation of 1,3-dithiol ring is of an envelope-type. A very short intramolecular sulfur-sulfur distance of 2.94 Å was observed. The compoundII (C11H9NS2) is monoclinic: P21/c,a=5.113(2),b=11.978(4),c=16.444(5) Å, β=98.00(5) deg. The conformation of the 1,4-dithiin rings is a half-chair. As compared to other 3,4-quinolinediyl bis-sulfides an elongated intramolecular sulfur-sulfur distance of 3.437(4) Å in dihydrodithiinoquinolineII was observed.
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Boryczka, S.; Maślankiewicz, A.; Wyszomiski, M.; Borowiak, T.; Kubicki, M.:Rec. Trav. Chim. Pays-Bas. 1990,109, 509.
Pluta, K.; Maślankiewicz, A.; Glowiak, T.J. Cryst. Spec. Res. 1993,23, 285.
Wyszomirski, M.; Gogoll, A.; Maślankiewicz, A.; Boryczka, S.Phosph. Sulf. Sil. 1991,59, 225.
Maślankiewicz, A.; Skrzypek, L.Synthesis 1986, 835.
Maślankiewicz, A.; Skrzypek, L.Polish. J. Chem. 1992,66, 1825.
Maślankiewicz, A.; Wysomirski, M.; Glowiak, T.; Gogoll, A.J. Cryst. Spec. Res. 1991,21, 559.
Syntex XTL/XTLE Structure Determination System; Syntex Analytical Instruments: Cupertino, CA, 1976.
International Tables for X-ray Crystallography Vol. IV: Kynoch Press: Birmingham, U.K., 1974.
Sheldrick, G.M.SHELX86. Program for crystal structure determination; University of Cambridge: England, 1986.
Bukowska-Strzyżewska, M.; Dobrowolska, W.; Glowiak, T.Acta Cryst,1980,B36, 3167.
Ferguson, G.; Kaitner, B.; Brewer, A.D.Acta Cryst. 1990,C46, 1284.
Kagabu, S.; Kaiser, C.; Keller, R.; Becker, P.G.; Muller, K-H.: Knothe, L.; Rihs, G.; Prinzbach, H.Chem. Ber. 1988,121, 741.
Lynton, H.; Cox, E.G.J. Chem. Soc. 1956, 4886.
Kobayashi, K.; Takahashi, M.; Kobayashi, H.J. Chem. Soc., Perkin Trans. II 1988, 427.
Maślankiewicz, A.; Wyszomirski, M.; Glowiak, T.J. Cryst. Spec. Res. 1990,20, 375.
Kulpe, S.; Seidel, I.Kristall Technik,1980,15, 3.
Pauling, L.The nature of the chemical bond (third edition); Cornell: Ithaca, 1960.
Wyszomirski, M.Ph.D. thesis, University of Wroclaw: Wroclaw, 1992.
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Part XXXI in the series of Azinyl Sulfides.
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Glowiak, T., Maślankiewicz, A., Wyszomirski, M. et al. X-ray structures of 1,3-dithiolo[4,5-c]quinoline and 2,3-dihydro-1,4-dithiino[5,6-c]quinoline. J Chem Crystallogr 25, 171–176 (1995). https://doi.org/10.1007/BF01666102
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DOI: https://doi.org/10.1007/BF01666102