Skip to main content
SpringerLink
Log in

Structure of [La(NO3)3(OH2)2(OHMe)(bipy)]·15-crown-5

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

[La(NO3)3(OH2)2(OHMe)(bipy)·15-crown-5 is monoclinic,P2t/n, witha=11.239(6),b=19.302(7),c=14.458(8) Å, β=92.47(5)°, andD calc=1.63 g cm−3 forZ=4. In the complex, two nitrogen atoms (from bipy) and nine oxygen atoms (six from three bidentate nitrate anions, two from water molecules, and one from a methanol molecule) coordinate to the La(III) ion forming a coordination polyhedron which approximates a skewed trigonal prism with an interpenetrating pentagon. The coordinated methanol and water molecules donate hydrogen bonds to the oxygen atoms of the crown ether forming polymeric hydrogen bonded chains which propagate along theac diagonal in the unit cell.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Rogers, R.D.; Rollins, A.N.; Etzenhouser, R.D.; Voss, E.J.; Bauer, C.B.Inorg. Chem. 1993,32, 3451, and references therein.

    Google Scholar 

  2. Lei, X.B.; Ji, Z.P.; Xiao, W.J.Chem. J. Chinese Univ. 1990,11. 565.

    Google Scholar 

  3. Al-Karaghouli, A.R.; Wood, J.S.Inorg. Chem. 1972,11, 2293.

    Google Scholar 

  4. Kravchenko, V.B.Zh. Strukt. Khim. 1972,13, 345.

    Google Scholar 

  5. Zhu, W.-X.; Yang, R.-N.; Zhao, J.-Z.; Luo, B.-S.; Chen, L.-R.Jiegou Huaxue (j. Struct. Chem.) 1990,9, 286.

    Google Scholar 

  6. Sheldrick, G.M.SHELX76, a Program for Crystal Structure Determination; University of Cambridge: England. 1976.

    Google Scholar 

  7. Sheldrick, G.M.SHELXS: Acta Cryst. 1990,A46, 467.

    Google Scholar 

  8. International Tables for X-Ray Crystallography. Vol. IV; Kynoch Press: Birmingham, U.K., 1974; pp. 72, 99, 149.

  9. Rogers, R.D.; Kurihara, L.I.Inorg. Chim. Acta 1987,129, 277.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Wuhan University, 430072, Wuhan, China

    Zhen Ping Ji

  2. Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, China

    Zhen Ping Ji

  3. Department of Chemistry, Northern Illinois University, 60115, DeKalb, Illinois

    Robin D. Rogers

Authors
  1. Zhen Ping Ji
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Robin D. Rogers
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ji, Z.P., Rogers, R.D. Structure of [La(NO3)3(OH2)2(OHMe)(bipy)]·15-crown-5. J Chem Crystallogr 24, 415–419 (1994). https://doi.org/10.1007/BF01666087

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01666087

Key Words

Search

Navigation