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Synthesis, characterization, and X-ray crystal structure of tris(1,10-phenanthroline)nickel(II) perchlorate hemihydrate

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Abstract

The title compound was synthesized and characterized by conventional methods and its X-ray crystal structure was determined. The complex crystallizes in the monoclinic space group C2/c with eight formula units in a cell of dimensions:a=36.714(4),b=15.746(2),c=12.337(2) Å; β=102.9(1)°. The structure is built up by alternate layers of octahedral [Ni(phen)3]2+ cations and perchlorate anions with water molecules which run in the direction of thea axis nearly parallel to thebc plane.

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Authors and Affiliations

  1. Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica, Chimica Fisica, Centro di Studio per la Strutturistica Diffrattometrica del C. N. R., Università di Parma, Viale delle Scienze, I-43100, Parma, Italy

    Laila Abdel-Rahman, Luigi P. Battaglia, Corrado Rizzoli & Paolo Sgarabotto

Authors
  1. Laila Abdel-Rahman
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  2. Luigi P. Battaglia
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  3. Corrado Rizzoli
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  4. Paolo Sgarabotto
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Abdel-Rahman, L., Battaglia, L.P., Rizzoli, C. et al. Synthesis, characterization, and X-ray crystal structure of tris(1,10-phenanthroline)nickel(II) perchlorate hemihydrate. J Chem Crystallogr 25, 629–632 (1995). https://doi.org/10.1007/BF01665968

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  • DOI: https://doi.org/10.1007/BF01665968

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