Abstract
The title compound crystallizes in the monoclinic space group P21/c, witha=10.449(2),b=11.555(1),c=10.854(2) Å, β=90.46(2)° andV=1310.3 Å3. ForZ=4 and F.W.=274.32 the calculated density is 1.39 g/cm3. The structure was solved by direct method, and refined by full-matrix least-squares methods toR=0.034 for 3013 observed reflections. The stereochemistry of the 6/5-ring-H-bonded moiety is found to be planar, the rings being fused at the C(8)−C(13) bond. The-NSO2Ph group is linked with the fused-6/5 H-bonded ring through the N(4)−S(1) bond and the phenyl ring in the group is disposed perpendicular to the former ring system. The structure of the ligand appears to be suitable for bis-chelate formation with metals such as Cu(II) or Ni(II).
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Hussain, M.S., Al-Arfaj, A.R. & Mazzah, A. Intramolecular short hydrogen bond: the structure of benzenesulphonylhydrazone derivative of salicylaldehyde. J Chem Crystallogr 25, 511–515 (1995). https://doi.org/10.1007/BF01665709
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DOI: https://doi.org/10.1007/BF01665709