Summary
The adsorbate-adsorbate association model (AA model) is used to describe the adsorption of binary gas mixtures on homogeneous adsorbents. The single and double associates are considered only, because most useful equations are obtained. The association parallel and normal to surface is discussed. The model of associates normal to surface explains theGonzalez andHolland adsorption isotherm.
Zusammenfassung
Zur Beschreibung der Adsorption einer binären Gasmischung an homogenen Adsorbentien wurde ein Modell über Adsorbat-Adsorbat-Assoziationen zu Grunde gelegt. Es wurden nur einfache und doppelte Assoziate betrachtet, weil diese Annahmen zu gut anwendbaren Gleichungen führen. Dabei wird die Assoziation sowohl normal als auch senkrecht zur Grenzfläche untersucht. Das Modell der Assoziate normal zur Grenzfläche führt zur Adsorptionsisotherme vonGonzalez undHolland.
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References
Myers, A. L., J. M. Prausnitz, American Institute Chemical Engineers11, 121 (1965).
Friedrich, R. 0., J. C. Mullins, Ind. Eng. Chem. Fundam.11, 439 (1972).
Sloan, E. D., J. C. Mullins, Ind. Eng. Chem. Fundam.14; 347 (1975).
Hoory, S. E., J. M. Prausnitz, Chem. Engng. Sci.22, 1025 (1967).
Bering, B. P., V. V. Serpinsky, Izv. Akad. Nauk SSSR, Otd. Khim. 406 and 1947 (1961).
Dubinin, M. M., B. P. Bering, V. V. Serpinsky, In: Recent Progress in Surface Science, vol. 2, pp. 28–32 (New York 1964).
Van Ness, H. C., Ind. Eng. Chem. Fundam.8, 464 (1969).
Sircar, S., A. L. Myers, Chem. Engng. Sci.28, 489 (1973).
Markbam, E. C., A. F. Benton, J. Am. Chem. Soc.53, 497 (1931).
Schay, G., P. Fejes, J. Szathmdry, Acta Chim. Hung.12, 299 (1957).
Jaroniec, M., Chemicke Zvesti29, 512 (1975).
Kemball, C., E. K. Kideal, E. A. Guggenheim, Trans. Faraday Soc.44, 948 (1948).
Ivanov, I. B., A. Martinov, in Physical Adsorption from Multicomponent Phase, Nauka, 1973 pp. 191–201 in Russian.
Lee, Ch. S., P. O. O'Connell, Ind. Eng. Chem. Fundam.13, 165 (1974).
Hill, T. L., J. Chem. Phys.14, 46 (1946).
Hill, T. L., J. Chem. Phys.14, 268 (1946).
Bussey, B. W, Ind. Eng. Chem. Fundamentals5, 103 (1966).
Gonzalez, A. J., G. D. Holland, American Institute Chemical Engineers16, 718 (1970).
Gonzalez, A. J., G. D. Holland, American Institute Chemical Engineers17, 470 (1971).
Jaroniec, M., W. Rudziński, Phys. Letters53 A, 59 (1975).
Jaroniec, M., W. Kudziński, Surface Sci.52, 641 (1975).
Jaroniec, M., J. Colloid Interf. Sci.52, 41 (1975).
Jaroniec, M., J. Colloid Interf. Sci.53, 422 (1975).
Jaroniec, M., W. Rudzigski, J. Low Temperature Phys.24, 253 (1976).
Jaroniec, M., J. Tóth, Colloid & Polymer Sci.254, 643 (1975).
Jaroniec, M., Phys. Letters56 A, 53 (1976).
Jaroniec, M., Z. Phys. Chem. Leipzig257, 449 (1976).
Kiselev, A. V., Dokl. Akad. Nauk SSSR117, 1093 (1957).
Kiselev, A. V., Kolloid Zh. SSSR20, 338 (1958).
Berezin, G. I., A. V. Kiselev, J. Colloid Interf. Sci.38, 227 (1972).
Berezin, G. I., A. V. Kiselev, R. T. Sagatelyan, V. A. Sinitsyn, J. Colloid Interf. Sci.38, 335 (1972).
Berezin, G. I., A. V. Kiselev, J. Colloid Interf. Sci.46, 203 (1974).
Karpihski, K., J. Garbacz, Ann. Soc. Chim. Pol.48, 803 (1974).
Garbacz, J., J. Colloid Interf. Sci.51, 352 (1975).
Jaroniec, M., Vuoto9, 36 (1976).
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Jaroniec, M. Adsorption of gas mixtures on homogeneous solid surfaces I. Model of double associates for adsorption of binary mixtures. Colloid & Polymer Sci 256, 1089–1094 (1978). https://doi.org/10.1007/BF01638300
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DOI: https://doi.org/10.1007/BF01638300