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Proton nuclear magnetic resonance in paramagnetic NiSO4 · 1 H2O

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Czechoslovak Journal of Physics B Aims and scope

Abstract

Parameters characterizing the magnetic interactions between the paramagnetic ions Ni2+ and the protons of crystalline water in powderedNiSO 4 · 1H 2O were derived from the field and temperature dependences of the second moment of NMR spectra. The Curie-Weiss constantΘ, magnetic momentμ i and the part of second momentM 2O corresponding to the nuclear dipoledipole interaction were evaluated from the experimental data. The parameters characterizing the local magnetic field acting on the proton-pairs were calculated and compared with those obtained from the analysis of the shape of the NMR spectrum.

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References

  1. Kroon J. D.: Philips Res. Rep.15 (1969) 501.

    Google Scholar 

  2. Oravcová J., Murín J., Rákoš M., Olčák D.: Czech. J. Phys. B28 (1978) 1146.

    Google Scholar 

  3. Murín J., Olčák D., Oravcová J., Rákoš M., Jelšovská K.: Czech. J. Phys. B31 (1981) 313.

    Google Scholar 

  4. Muriń J.: Czech. J. Phys. B36 (1986) 740.

    Google Scholar 

  5. Murín J., Olčák D., Oravcová J., Rákoš M., Skokanová Z., Kročan J.: Czech. J. Phys. B30 (1980) 450.

    Google Scholar 

  6. Murín J.: Czech. J. Phys. B36 (1986) 551.

    Google Scholar 

  7. Slichter C. P.: Principles of Magnetic Resonance. Springer-Verlag, Berlin-Heidelberg-New York, 1980 (Russian translation-Mir, Moscow, 1981).

    Google Scholar 

  8. Pake G. E.: J. Chem. Phys.16 (1948) 326.

    Google Scholar 

  9. Abragam A.: The Principles of Nuclear Magnetism. Clarendon Press, Oxford, 1961 (Russian, translation-Moscow, 1963).

    Google Scholar 

  10. Krinčik G. S.: Physics of Magnetic Phenomena (in Russian), Moscow, 1976.

  11. Oswald H. R.: Helv. Chim. Acta48 (1965) 590.

    Google Scholar 

  12. Le Fur Y., Coing-Boyat J., Bass G.: C. R. Acad. Sci. Paris C262 (1966) 532.

    Google Scholar 

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Authors and Affiliations

  1. Department of Physics, Technical University, Park Komenského 2, 041 20, Košice, Czechoslovakia

    K. Jelšovská & J. Murín

Authors
  1. K. Jelšovská
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  2. J. Murín
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The authors express their grateful acknowledgement to Prof. Dr. hab. Z. Pajak, Dr. S. GIo-winkowski, Dr. J. Kapturczak and Ing. W. Porzuckoviak from Institute of Physics, A. Mickiewicz University in Poland for their help in NMR measurements and fruitful discussions.

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Jelšovská, K., Murín, J. Proton nuclear magnetic resonance in paramagnetic NiSO4 · 1 H2O. Czech J Phys 39, 1161–1170 (1989). https://doi.org/10.1007/BF01605400

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  • DOI: https://doi.org/10.1007/BF01605400

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