Abstract
A new perturbative prescription is proposed. It differs from the textbook Rayleigh-Schroedinger (RS) theory by the assumption of the user's incomplete knowledge of the unperturbed spectra. We only need a single eigenvalue and eigenstate ofH 0. In our quasi-RS (QRS) formulas, this eigenstate keeps its “unperturbed” RS interpretation, while the role of the (non-available) RS unperturbed spectrum is taken over by certain auxiliary matrix continued fractions. These quantities represent a weaker though entirely sufficient “compressed” information aboutH 0 and, after a suitable partitioning, enable one to combine the usual (i.e., sufficiently simple, here: harmonic-oscillator) working basis ¦n> with a very broad (here: arbitrary Padé-anharmonic) class of the zero-order HamiltoniansH 0.
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Znojil, M. The exact bound-state ansaetze as zero-order approximations in perturbation theory I. The formalism and padé oscillators. Czech J Phys 41, 397–408 (1991). https://doi.org/10.1007/BF01597944
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DOI: https://doi.org/10.1007/BF01597944