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The fifth virial coefficients of fused hard sphere fluids

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Czechoslovak Journal of Physics B Aims and scope

Abstract

The virial coefficients up toB 5 of 34 fused hard sphere models have been computed using about (4–10)×105 trial configurations of a modified Monte Carlo integration method. The principle of the conformal behaviour of hard particle systems is tested against these data. It is found that while for the fourth coefficient the principle is satisfied in all the cases, the fifth coefficients exhibit more complicated behaviour and do not conform, in general, to this principle.

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Authors and Affiliations

  1. Institute of Chemical Process Fundamentals, Czechosl. Acad. Sci., Suchdol, 165 02, Praha 6, Czechoslovakia

    I. Nezbeda & B. Tříska

  2. Department of Physical Chemistry, Institute of Chemical Technology, 166 28, Praha 6, Czechoslovakia

    A. Malijevský

Authors
  1. I. Nezbeda
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  2. B. Tříska
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  3. A. Malijevský
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Nezbeda, I., Tříska, B. & Malijevský, A. The fifth virial coefficients of fused hard sphere fluids. Czech J Phys 38, 1234–1242 (1988). https://doi.org/10.1007/BF01597292

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  • DOI: https://doi.org/10.1007/BF01597292

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