Abstract
High temperature properties of triplet excitations in TCNQ-salts are theoretically studied. Formulas for the energy and concentration of triplet excitons as functions of temperature are obtained. The static magnetic susceptibility of triplet excitons is calculated. A possible appearance of short range order in the excitation density is discussed. A high-concentration modification of the molecular exciton theory is used throughout the paper.
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I would like to express thanks to Dr. W.Siebrand of N.R.C., Ottawa, for introducing me into problems in charge-transfer crystals. I also thank Professor M.Trlifaj for interesting discussions.
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Král, K. Triplet excitations at high temperatures in 1:1 TCNQ-salts. Czech J Phys 23, 100–109 (1973). https://doi.org/10.1007/BF01596883
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DOI: https://doi.org/10.1007/BF01596883