Skip to main content
Log in

Triplet excitations at high temperatures in 1:1 TCNQ-salts

  • Published:
Czechoslovak Journal of Physics B Aims and scope

Abstract

High temperature properties of triplet excitations in TCNQ-salts are theoretically studied. Formulas for the energy and concentration of triplet excitons as functions of temperature are obtained. The static magnetic susceptibility of triplet excitons is calculated. A possible appearance of short range order in the excitation density is discussed. A high-concentration modification of the molecular exciton theory is used throughout the paper.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Nordio P. L., Soos Z. G., McConnell H. M., Ann. Rev. Phys. Chem.17 (1966), 237.

    Google Scholar 

  2. Melby L. R., Harder R. J., Hertler W. R., Mahler W., Benson R. E., Mochel W. E., J. Am. Chem. Soc.84 (1962), 3374.

    Google Scholar 

  3. Epstein A. J., Etemad S., Garito A. F., Heeger A. J., Physical ReviewB 5 (1972), 952.

    Google Scholar 

  4. Soos Z. G., J. Chem. Phys.43 (1965), 1121.

    Google Scholar 

  5. Doniah S., Advan. Phys.18 (1969), 819.

    Google Scholar 

  6. Agranovich V. M., Teoriya eksitonov. Moscow 1968.

  7. Lalovich D. I., Toshich B. S., Zhakula R. B., Phys. Rev.178 (1969), 1472.

    Google Scholar 

  8. Král K., Czech. J. Phys.B 22 (1972), 571.

    Google Scholar 

  9. Jortner J., Rice S. A., Katz J. L., J. Chem. Phys.42 (1965), 309.

    Google Scholar 

  10. Zubarev D. N., Usp. Fiz. Nauk71 (1960), 71. English translation: Soviet Phys. Usp.3 (1960), 320.

    Google Scholar 

  11. White R. M., Quantum theory of magnetism. McGraw-Hill, 1970.

  12. Chesnut D. B., Suna A., J. Chem. Phys.39 (1963), 146.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

I would like to express thanks to Dr. W.Siebrand of N.R.C., Ottawa, for introducing me into problems in charge-transfer crystals. I also thank Professor M.Trlifaj for interesting discussions.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Král, K. Triplet excitations at high temperatures in 1:1 TCNQ-salts. Czech J Phys 23, 100–109 (1973). https://doi.org/10.1007/BF01596883

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01596883

Keywords

Navigation