Skip to main content
Log in

Bounds for energies of radial lithium

  • Original Papers
  • Published:
Zeitschrift für angewandte Mathematik und Physik ZAMP Aims and scope Submit manuscript

Summary

This article presents the first application of a new method for lower bounds to eigenvalues of operators of the kind that describe the energies of atoms and ions. We consider radial models of these atoms and carry out a detailed analysis for radial lithium. The calculations yield the required displacement of essential spectra and give lower bounds where all other methods fail.

Zusammenfassung

Es wird in vorliegender Arbeit die erste Anwendung einer neuen Methode für untere Schranken auf Eigenwerte von solchen Operatoren, die die Energien von Atomen und Ionen beschreiben, dargelegt. Wir betrachten Radialmodelle dieser Atome und führen eine eingehende Analyse für Radiallithium durch. Die Rechnungen ergeben die erforderliche Verschiebung wesentlicher Spektren und liefern untere Grenzen, während alle anderen Methoden erfolglos bleiben.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. E. Balslev,Group Representations and Quantum Mechanics (SUNY at Buffalo, 1969).

  2. E. Balslev,Spectral Theory of Schrödinger Operators of Manybody Systems with Permutation and Rotation Symmetries (SUNY at Buffalo, 1970).

  3. D. W. Fox,Lower Bounds for Eigenvalues with Displacement of Essential Spectra, Techn. Report, Appl. Math. Group, Appl. Phys. Lab. (The Johns Hopkins University, January 1969), to appear, SIAM J. Math. Anal.3, No. 4 (1972).

  4. D. W. Fox,Lower Bounds to Eigenvalues with Displacement of Essential Spectra, Notices, Am. Math. Soc.16, No. 5, 800 (1969).

    Google Scholar 

  5. D. W. Fox andV. G. Sigillito,Lower Bounds for the Radial Lithium Atom's Lowest Eigenvalue, Abstracts, SIAM Nat. Meeting (July 1970).

  6. D. W. Fox andV. G. Sigillito,Lower and Upper Bounds to Energies of Radial Lithium, Chem. Phys. Lett.13, No. 1, 85–87 (1972).

    Google Scholar 

  7. T. Ikeba andT. Kato,Uniqueness of the Self-Adjoint Extension of Singular Elliptic Operators, Arch. Rat. Mech. Anal.9, 77–92 (1962).

    Google Scholar 

  8. A. G. Sigalov,The Main Mathematical Problem in the Theory of Atomic Spectra, Russian Math. Surveys22, 1–18 (1967).

    Google Scholar 

  9. J. C. Slater,Quantum Theory of Atomic Structure, Vol. I (McGraw-Hill, New York 1960).

    Google Scholar 

  10. E. P. Wigner,Group Theory and Its Application to the Quantum Mechanics of Atomic Spectra Academic Press, New York 1959).

    Google Scholar 

  11. G. M. Žislin andA. G. Sigalov,On the Spectrum of the Energy Operator for Atoms with Fixed Nuclei on Subspaces Corresponding to Irreducible Representations of a Permutation Group, Izv. Akad. Nauk SSSR [Ser. mat. 29], p. 835–860 (1965); Transl. A.M.S. [Ser. 2], Vol. 91, p. 263–296.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

This work has been supported by the Department of the Navy, Naval Ordnance Systems Command under Contract Number N00017-72-C-4401.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fox, D.W., Sigillito, V.G. Bounds for energies of radial lithium. Journal of Applied Mathematics and Physics (ZAMP) 23, 392–411 (1972). https://doi.org/10.1007/BF01595480

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01595480

Keywords

Navigation