Skip to main content
Log in

Visible photoluminescence from hydrogenated amorphous carbon films prepared by pulsed laser ablation of polymethyl methacrylate (PMMA)

  • Invited Paper
  • Published:
Applied Physics A Aims and scope Submit manuscript

Abstract

Visible photoluminescence (PL) has been observed from the hydrogenated amorphous carbon (a-C:H) films prepared by ArF pulsed laser ablation of polymethyl methacrylate (PMMA) in the presence of hydrogen gas (H2). With increasing hydrogen concentration the PL intensity increases and the intensity maximum blue-shifted. The PL intensity also increases after hours of light illumination, exhibiting a light soaking enhancement. Increasing the deposition temperature decreases the PL and increases the ratio of sp3/sp2 bonds.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. E. Sutcliffe, and R. Srinivasan: J Appl. Phys.60, 3315 (1986); R. Srinivasan: J. Appl. Phys.73, 2743 (1993) and references therein

    Google Scholar 

  2. S. Kuper, S. Modaressi, M. Stuker: J. Phys. Chem.94, 7514 (1990)

    Google Scholar 

  3. G.B. Blanchet and C.R. Fincher, Appl. Phys. Lett. 65, 1311 (1994)

    Google Scholar 

  4. A. Costela, J.M. Figuera, F. Florid, I. Garcia-Moreno, E.P. Collar, R. Sastre: Appl. Phys.A60, 261 (1995)

    Google Scholar 

  5. I.S. Athwal, A. Mele, E.A. Ogryzlo: Diamond and Related Materials1, 731 (1992)

    Google Scholar 

  6. S. Latsch and H. Hiraoka: JOM: The Journal of the Minerals, Metals and Materials Society46, 64 (1994); S. Latsch, H. Hiracka, R.F. Xiao: US patent No. 5,368,681, 1994

    Google Scholar 

  7. J. Robertson: Prog. Solid State Chem.21, 199 (1991)

    Google Scholar 

  8. F. Demichelis, S. Schreiter, A. Tagliaferro: Phys. Rev.B51, 2143 (1995)

    Google Scholar 

  9. R.F. Xiao, L.C. Ng, C. Jiang, Z.Y. Yang, G.K.L. Wong: Thin Solid Films260, 10 (1995)

    Google Scholar 

  10. J. Robertson: Diamond and Related Mater.4 (1995) 297, and references therein

    Google Scholar 

  11. R. Kubo: J. Phys. Soc. Jap.17, 975 (1962)

    Google Scholar 

  12. W.F. Maddams: Analysis of Polymer Systems, edited by L.S. Bark and N.S. Allen (Applied Science Pub. Ltd., 1982), p. 51

  13. B. Dischker: Amorphous Hydrogenated Carbon Films, E-MRS Symp. Proc. Vol. 17, edited by P. Koidl and P. Oelhafen (Les Editions, de Physique, Paris, 1987), p. 189

    Google Scholar 

  14. X.-M. Tang, J. Weber, S.N. Mikhailov, C. Muller, W. Hanni, H.E. Hintermann: J. of Non-Cryst. Solids185, 145 (1995)

    Google Scholar 

  15. B. Discher, A. Bubenzer, P. Koidl: Solid State Commun48, 105 (1983)

    Google Scholar 

  16. C. De Martino, F. Demichelis, A. Tagliaferro: Diamond and Related Mater.4, 1210 (1995)

    Google Scholar 

  17. W. Jacob, W. Möller: Appl. Phys. Lett.63, 1771 (1993)

    Google Scholar 

  18. T. Sato, S. Furuno, S. Iguchi, M. Hanabusa: Appl. Phys.A45, 355 (1988); D.L. Pappas, K.L. Saenger, J. Bruley, W. Krakow, J.J. Cuomo, T. Gu, R.W. Collins: J. Appl. Phys.71, 5675 (1992)

    Google Scholar 

  19. B. Dischler, E. Bayer: J. Appl. Phys.68, 1237 (1990)

    Google Scholar 

  20. M. Koos, I. Pocsik, L. Toth: Appl. Phys. Lett.65, 2245 (1994)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Z.F. Li is on leave from Department of Physics, Nanjing University, Nanjing 210093, P.R. China.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Li, Z.F., Yang, Z.Y. & Xiao, R.F. Visible photoluminescence from hydrogenated amorphous carbon films prepared by pulsed laser ablation of polymethyl methacrylate (PMMA). Appl. Phys. A 63, 243–246 (1996). https://doi.org/10.1007/BF01567876

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01567876

PACS

Navigation