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Crystal structure of di-μchlorobis{[bis(3-methylrhodanine)]copper(I)}-3-methylrhodanine

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Abstract

The crystal structure of

has been determined by X-ray analysis. The monoclinic cell, space groupC2/c witha=12.956(2),b=15.873(2),c=17.437(2) Å,β=105.90(1)° contains eight formula units. The structure was determined using MoKα. automatic diffractometer X-ray data and refined by full-matrix least squares toR=0.039 for 3025 reflections. Two crystallographically independent 3-memylrhodanines are coordinated to copper, and another 3-methylrhodanine is not bonded to copper and is in a disordered position around the crystallographic two-fold axis. In the dimeric structure with bridging chlorine atoms, the copper is in tetrahedral coordination with two chlorine and two sulfur atoms. The copper-copper distance is 2.906(1) Å.

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Authors and Affiliations

  1. Crystallography Laboratory, University of Nijmegen, Toernooiveld, 6525, ED Nijmegen, The Netherlands

    F. G. Moers, Paul T. Beurskens, J. H. Noordik & J. M. M. Smits

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  1. F. G. Moers
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  2. Paul T. Beurskens
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  3. J. H. Noordik
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  4. J. M. M. Smits
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Moers, F.G., Beurskens, P.T., Noordik, J.H. et al. Crystal structure of di-μchlorobis{[bis(3-methylrhodanine)]copper(I)}-3-methylrhodanine. Journal of Crystallographic and Spectroscopic Research 16, 107–113 (1986). https://doi.org/10.1007/BF01566051

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  • DOI: https://doi.org/10.1007/BF01566051

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