Abstract
The crystal structure of glycinium monophenylphosphate [NHsk3/+CH2COOH·C6H5OPO3H− has been determined. The crystals are orthorhohombic:Pbca (NO. 61),a=26.001(3),b=7.423(2),c=11.273(2) Å,Z=8. The structure was solved by direct methods, are refined toR=0.035 for 1499 independent reflections. The crystal structure is stabilized by a three-dimensional network of hydrogen bonds. The phosphate group is involved in five H bonds: three N⋯O and two O⋯O bonds, with the shortest distances 2.745(3) and 2.608(2) Å, respectively. The glycine cation is entirely planar, and a cationo-anionic form of the title compound has also been confirmed in solution byIR studies.
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Głowiak, T., Szemik, A.W. Crystal structure and spectroscopic properties of glycinium monophenylphosphate. Journal of Crystallographic and Spectroscopic Research 16, 79–89 (1986). https://doi.org/10.1007/BF01566048
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DOI: https://doi.org/10.1007/BF01566048