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Vapor pressures and gas-phasePVT data for 1-Chloro-1,2,2,2-tetrafluoroethane (R124)

Abstract

We present new data for the vapor pressure andPVT surface of 1-chloro-1,2,2,2-lelralluoroethane (designated R124 by the refrigeration industry) in the temperature range 278–423 K. ThePVT data are for the gas phase at densities up to 1.5 times the critical density. Correlating equations are given for the vapor pressures from 220 K to the critical temperature, 395.43 K, and for thePVT surface at densities up to 2 mol · L−1 (approximately 0.5 times the critical density). Second and third virial coefficients have been derived from thePVT measurements.

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References

  1. M. Waxman and J. R. Hastings,J. Res. Natl. Bur. Stand. 75C:106 (1971); D. Linsky, J. M. H. Levelt-Sengers, and H. A. Davis,Rev. Sci. Instrum. 58:817 (1987).

    Google Scholar 

  2. M. Waxman, H. A. Davis, M. Horowitz, and B. Everhart,Rev. Sci. Instrum. 55:1467 (1984).

    Google Scholar 

  3. L. A. Weber and A. Silva,J. Chem. Eng. Data (in press).

  4. J. W. Schmidt and M. R. Moldover, personal communication.

  5. A. R. H. Goodwin, D. R. Defibaugh, and L. A. Weber,Int. J. Thermophys. 13:837 (1992).

    Google Scholar 

  6. L. A. Weber,Int. J. Refrig. 17:117 (1994).

    Google Scholar 

  7. I. Gallagher, M. McLinden, G. Morrison, M. Huber, and J. Ely, NIST Standard Reference Database 23, Thermodynamic Properties of Refrigerants and Refrigerant Mixtures (REFPROP).

  8. M. L. Japas and J. M. H. Levelt-Sengers,AIChE J. 35:705 (1989).

    Google Scholar 

  9. V. G. Niesen, L. J. Van Poolen, and S. L. Outcalt, submitted for publication.

  10. I. R. Shankland, R. S. Basu, and D. P. Wilson,ASHRAE Trans. 96:2 (1990).

    Google Scholar 

  11. H. Kubota, Y. Tanaka, T. Makita, H. Kashiwagi, and M. Noguchi,Int. J. Thermophys. 85:9 (1988).

    Google Scholar 

  12. M. B. Ewing and K. N. Marsh,J. Chem. Thermophys. 11:793 (1979).

    Google Scholar 

  13. R. D. McCarty,Experimental Thermodynamics, Vol. 11. Experimental Thermodynamics of Non-reacting Fluids, B. Le Neindre and B. Vodar, eds. (Butterworths, London, 1968).

    Google Scholar 

  14. J. O. Hirschfelder, C. F. Curtis, and R. B. Bird.Molecular Theory of Gases and Liquids (Wiley, New York, 1954).

    Google Scholar 

  15. J. Sandarusi, personal communication (1991).

  16. K. A. Gillis. Int. J. Thermophys. (in press).

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Boyes, S.J., Weber, L.A. Vapor pressures and gas-phasePVT data for 1-Chloro-1,2,2,2-tetrafluoroethane (R124). Int J Thermophys 15, 443–460 (1994). https://doi.org/10.1007/BF01563707

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  • DOI: https://doi.org/10.1007/BF01563707

Key Words

  • 1-Chloro-1,2,2,2-tetrafluoroethane
  • density
  • gas-phasePVT
  • refrigerant R 124
  • saturated vapor density
  • vapor pressures
  • virial coefficients