Abstract
Asymmetric polyfluorinated ketones RFCOR are formed by treating various derivatives of (polyfluoro)alkanoic acids (esters, anhydrides, acid chlorides) with lithium tetraalkylaluminates (“ate-complexes”). The highest yields of the ketones (65–78 %) were obtained from (polyfluoro)alkanoyl chlorides.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A. Lovelace, D. A. Rausch, and W. Postelnek,Aliphatic Fluoro-Containing Compounds, Reinhold, New York, 1958.
A. V. Kuchin, R. A. Nurushev, A. Yu. Spivak, and G. A. Tolstikov,Zh. Obshch. Khim., 1986,56, 2306 [J. Gen. Chem., 1986,56 (Engl. Transl.)].
O. G. Khomutov, V. I. Filyakova, A. V. Kuchin, K. I. Pashkevich, and G. A. Tolstikov,Izv. Akad. Nauk, Ser. Khim., 1992, 2339 [Bull. Russ. Acad. Sci., Div. Chem. Sci., 1992,41, 1834 (Engl. Transl.)].
Author information
Authors and Affiliations
Additional information
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1066–1067, June, 1994.
Rights and permissions
About this article
Cite this article
Pashkevich, K.I., Khomutov, O.G., Filyakova, V.I. et al. Synthesis of polyfluorinated ketonesvia the ate-complexes. Russ Chem Bull 43, 1002–1003 (1994). https://doi.org/10.1007/BF01558066
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01558066