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Dimericd- anddl-dysprosium(iii) tartrates: paramagnetic birefringence, molecular mechanics, stereoselectivity

  • Physical Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The molar constants of paramagnetic birefringence (PBR) for the dimeric dysprosium(iii)d- anddl-tartrates, Dy2(d-Tart)(l-Tart)2− (1) and Dy2(d-Tart)2 2− (2) have been determined by means of pH-metric and PBR measurements. The simulation of the structure of the ligand and solvate environment has been carried out using the method of molecular mechanics (Dashevsky-Plyamovaty model, the MIND program). In addition to the four oxygen atoms from the ligand, each DyIII ion coordinates four molecules of water and a Na+ ion.

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Authors and Affiliations

  1. V. I. Ul'yanov-Lenin Kazan' State University, 18 ul. Lenina, 420008, Kazan', Russian Federation

    V. V. Chevela, S. N. Matveev, Yu. I. Salnikov, V. E. Semyonov & S. G. Bezryadin

  2. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420062, Kazan', Russian Federation

    S. G. Vul'fson

Authors
  1. V. V. Chevela
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  2. S. G. Vul'fson
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  3. S. N. Matveev
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  4. Yu. I. Salnikov
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  5. V. E. Semyonov
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  6. S. G. Bezryadin
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1029–1032, June, 1994.

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Chevela, V.V., Vul'fson, S.G., Matveev, S.N. et al. Dimericd- anddl-dysprosium(iii) tartrates: paramagnetic birefringence, molecular mechanics, stereoselectivity. Russ Chem Bull 43, 964–967 (1994). https://doi.org/10.1007/BF01558058

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  • DOI: https://doi.org/10.1007/BF01558058

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