Abstract
Ammonia, NH3 or ND3, is vaporized upon a cold substrate (20–100 K) and irradiated with electrons of energies from 0.2 to 6 keV. The different EPR spectra show hyperfinestructure and may be ascribed to centers of the type H −2 , D −2 , (NH −2 )−, (ND −2 )−. With respect to electrostatic charge a chemical decomposition of ammonia must be assumed. No electronic centers are found, which could be compared with the solvated electrons known in liquid metal-ammonia-solutions or quenched solid metal-ammonia-layers.
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Meinem hochverehrten Lehrer, Herrn Prof. Dr. R. Hilsch, danke ich für die Anregung und Förderung der Arbeit. Hilfsmittel verdanke ich der Akademie der Wissenschaften in Göttingen.
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Beuermann, G. Elektronenspinresonanz von elektronenbestrahlten Ammoniakschichten. Z. Physik 247, 25–31 (1971). https://doi.org/10.1007/BF01557851
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DOI: https://doi.org/10.1007/BF01557851