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Precipitation and complex solubility of zirconium sulfate

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Summary

The solubility boundaries of systems obtained by mixing aqueous zirconium nitrate solutions with solutions of lithium-, potassium-, or magnesium-sulfate were determined as a function of pH. Distinct complex solubility ranges have been established in the excess of zirconium and sulfate salts, respectively.

Zusammenfassung

Die Löslichkeitsgrenzen von Zirkoniumsulfat wurden in Abhängigkeit von pH tyndallometrisch bestimmt. Das Zirkoniumsulfat wurde durch Fällung von wässerigen Zirkoniumnitrat-Lösungen mit Lithium-, Kaliumoder Magnesiumsulfat-Lösungen dargestellt. Im Überschuß von Zirkonium- oder Sulfatsalzen wurde eine ausgeprägte Komplexbildung beobachtet.

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Author notes

  1. E. Matijević & M. Kerker

    Present address: Department of Chemistry, Clarkson College of Technology, Potsdam, N.Y., USA

  2. A. Watanabe

    Present address: Institute of Chemical Research, Kyoto University of Industrial Arts and Textile Fibers, Matsugasaki, Kyoto, Japan

Authors and Affiliations

  1. Institute of Colloid and Surface Science, USA

    E. Matijević,  A. Watanabe & M. Kerker

  2. Department of Chemistry, Clarkson College of Technology, Potsdam, N.Y., USA

    A. Watanabe

Authors
  1. E. Matijević
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  2. A. Watanabe
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  3. M. Kerker
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Additional information

Supported by the U.S. Army Research Office (Durham), Grant No. DA-ARO(D)-31-124-G-656.

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Matijević, E., Watanabe, A. & Kerker, M. Precipitation and complex solubility of zirconium sulfate. Kolloid-Z.u.Z.Polymere 235, 1200–1203 (1969). https://doi.org/10.1007/BF01542529

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  • DOI: https://doi.org/10.1007/BF01542529

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