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Cation removal and lattice alteration of a biotite by a resin charged with different cations

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  • Colloid Science
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Summary

A suspension of a biotite was shaken with a synthetic cation exchanger. Alteration of the mineral lattice and amounts of cations taken up by the resin as a function of time and species of the cations with which the resin was originally saturated, was studied.

A H+–charged resin first caused an expansion, then a contraction, but later the lattice seemed to have been completely broken down.

When the resin was originally saturated with NH4 + or Ca++ no evident change of the basal spacing was observed.

Both Na+– and Mg++–charged resin caused expansions of the lattice with the consequent formation of a vermiculite-like mineral.

Zusammenfassung

Eine Biotitsuspension wurde mit einem synthetischen Kationenaustauscher behandelt. Der Einfluß auf das Gitter und die vom Austauscher gebundenen Kationen wurde in Abhängigkeit von der Zeit und von der Art der ursprünglich am Austauscher gebundenen Kationen untersucht. Ein mit einem H+beladener Austauscher verursacht zunächst eine Schichtaufweitung, dann eine Kontraktion, bevor das Gitter vollständig zerstört wird. Wenn der Austauscher mit NH+ 4 oder Ca++ beladen war, wurde keine merkliche Anderung des Schichtabstandes beobachtet. Mit Na+ und Mg++-Austauschern trat eine Gitteraufweitung auf unter Bildung vermikulitähnlicher Minerale.

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Authors and Affiliations

  1. Department of Soil Science, Agricultural University of Norway, 1432 Ås-NLH, Norway

    Harald Bergseth

  2. Soils Dept., Faculty of Agric., Cairo Univ., Giza, Egypt

    Sh. I. Abdel-Aal

Authors
  1. Harald Bergseth
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  2. Sh. I. Abdel-Aal
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Bergseth, H., Abdel-Aal, S.I. Cation removal and lattice alteration of a biotite by a resin charged with different cations. Colloid & Polymer Sci 254, 103–107 (1976). https://doi.org/10.1007/BF01526746

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  • DOI: https://doi.org/10.1007/BF01526746

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