Summary
Optical diffraction techniques are used to study the validity of a two-phase model for the structure of fibres. It is shown that the existence of an intermediate state of order renders measurements of ‘percentage crystallinity’ invalid, and a paracrystalline structure for nylon is proposed.
Zusammenfassung
Die Technik der optischen Beugung wurde angewandt, um die Gültigkeit eines Zwei-Phasen-Modells für die Struktur von Fasern zu prüfen. Es läßt sich zeigen, daß die Existenz einer intermediären Ordnung die Messungen von prozentualer Kristallinität ungültig macht und daß eine parakristalline Struktur für Nylon vorzuschlagen ist.
Similar content being viewed by others
References
Bonart, R., R. Hosemann, F. Motzkus, and H. Ruck, Norelco Rep. 7, 88 (1960).
Eisler, P., The Technology of Printed Circuits (London 1959).
Farrow, G. and I. M. Ward, Polymer 1, 330–339 (1960).
Goppel, J. M. and I. J. Arlmann, Appl. Sci. Res. A1, 462–474 (1949).
Hermans, P. H. and A. Weidinger, J. Appl. Phys. 19, 491–506 (1948).
Hosemann, R., Z. Physik 128, 1–35, 465–492 (1950).
Hosemann, R., Polymer 3, 349 (1962).
Hosemann, R. and S. N. Bagchi, Direct Analysis of Diffraction by Matter (Amsterdam 1962).
Hosemann, R. and R. Bonart, Kolloid-Z. 152, 53–57 (1957).
Hughes, W. and C. A. Taylor, J. Sci. Instr. 30, 105 bis 110 (1953).
Hyndman, D. and G. E. Origlio, J. Polymer Sci. 39, 556–558 (1959).
Kolb, H. J. and E. F. Izard, J. Appl. Phys. 20, 564–575 (1949).
Krimm, S. and A. V. Tobolsky, J. Polymer Sci. 7, 57–76 (1951).
Matthews, J. L., H. S. Peiser, and R. B. Richards, Acta Cryst. 2, 85–90 (1949).
Matsuoka, S., J. Appl. Phys. 32, 2334–2336 (1961).
Miller, R. L. and L. E. Nielsen, J. Polymer Sci. 55, 643–656 (1961).
Onogi, S., K. Sasaguri, and T. Adachi, J. Polymer Sci. 58, 1–17 (1962).
Ruland, W., Acta Cryst. 14, 1180 (1961).
Sobue, H. and Y. Tabata, J. Polymer Sci. 39, 427–433 (1959).
Starkweather, H. W. and R. E. Moynihan, J. Polymer Sci. 22, 363–368 (1956).
Stern, P. G., C. A. Taylor and E. C. Yeadon, Presented at the Conference of the X-ray Analysis Group, British Institute of Physics and the Physical Society, University of Edinburgh, Edinburgh, Scotland, April 8–9 (1965).
Stern, P. G. and E. Segerman, Nature, Lond. (in press 1966).
Taylor, C. A. and B. J. Thompson, J. Sci. Instr. 35, 294–297 (1958).
Taylor, C. A. and H. Lipson, Optical Transforms, London (1964).
Tiensuu, V. J, E. Ergun, and L. E. Alexander, J. Appl. Phys. 35, 1718–1720 (1964).
Yeadon, E. C., Ph. D. Thesis (Manchester 1961).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Stern, P.G. Experimental evidence for an intermediate state of order in polymers. Kolloid-Z.u.Z.Polymere 215, 140–145 (1967). https://doi.org/10.1007/BF01520394
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01520394