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Heterogeneous exchange of precipitates

VI. Exchange of ferric ion between an aqueous ferric chloride solution and colloidal beta ferric oxide monohydrate obtained by slow hydrolysis

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Summary

The heterogeneous exchange of ferric ion between a labelled aqueous ferric chloride solution and the colloidalβ-FeOOH, prepared by slow hydrolysis of a ferric chloride solution at 100 °C, was investigated at room temperature.

Contrary to previously described ferric (hydr)oxides, originating from freshly formed “amorphous” precipitate, theβ-FeOOH showed no exchange. This was attributed to a well ordered crystal lattice related to the slow formation of the solid phase.

The radioactive nuclide54Mn, present without isotopic carrier in the labelling59FeCl3 solution and introduced into the liquid phase, remained in the liquid phase.

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References

  1. Wolf, R. H. H., M. Mirnik, andB. Težak, Kolloid-Z. u. Z. Polymere205, 111 (1965).

    Article  CAS  Google Scholar 

  2. Lamb, A. B., andA. G. Jacques, J. Amer. Chem. Soc.60, 967, 1215 (1938);Gyani, B. P. andR. Misra, J. Indian Chem. Soc.31, 499 (1954);Težak, B. andR. Wolf, Arhiv Kem.25, 39 (1953).

    Article  CAS  Google Scholar 

  3. Weiser, H. B. andW. O. Milligan, J. Amer. Chem. Soc.57, 238 (1935).

    Article  CAS  Google Scholar 

  4. Wahl, A. C. andN. A. Bonner, Radioactivity Applied to Chemistry (New York, (London 1951).

  5. Wolf, R. H. H., Kolloid-Z. u. Z. Polymere205, 120 (1965).

    Article  CAS  Google Scholar 

  6. Kolthoff, I. M. andB. Moskovitz, J. Amer. Chem. Soc.58, 777 (1936).

    Article  CAS  Google Scholar 

  7. Nightingale, E. R. andR. F. Benck, Anal. Chem.32, 566 (1960).

    Article  Google Scholar 

  8. Watson, J. H. L., R. R. Cardell Jr., andW. Heller, J. Phys. Chem.66, 1757 (1962).

    CAS  Google Scholar 

  9. Buser, W. andU. Imobersteg, Helv. Chim. Acta37, 2345 (1954).

    Article  CAS  Google Scholar 

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Author notes

  1. R. H. H. Wolf

    Present address: Department of Physical Chemistry, Faculty of Sciences, University of Zagreb, Zagreb, Yugoslavia

Authors and Affiliations

  1. Laboratory of Radiochemistry, Institute “Rudjer Bošković”, Zagreb

    R. H. H. Wolf, M. Mirnik & B. Težak

  2. Department of Physical Chemistry, Faculty of Sciences, University of Zagreb, Zagreb, Yugoslavia

    M. Mirnik & B. Težak

Authors
  1. R. H. H. Wolf
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  2. M. Mirnik
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  3. B. Težak
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Additional information

Contribution number 113 from the Department of Physical Chemistry, Faculty of Sciences, University of Zagreb.

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Wolf, R.H.H., Mirnik, M. & Težak, B. Heterogeneous exchange of precipitates. Kolloid-Z.u.Z.Polymere 205, 118–119 (1965). https://doi.org/10.1007/BF01507974

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  • DOI: https://doi.org/10.1007/BF01507974

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