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Structure des savons alcalins

IV. Disavons de lithium, sodium, potassium, rubidium et césium

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Summary

This is a systematic x-ray diffraction study of the structure of alkali-metal di-soaps as a function of temperature.

Two types of structure have been identified. The first is lamellar with both polar groups and paraffin chains in the crystalline state. The second is also lamellar, but with polar groups and paraffin chains in the liquid state.

These structures have been discussed and compared to those of usual alkali-metal and alkaline-earth soaps.

Zusammenfassung

Aus röntgenographischen Daten wurde die Struktur der Lithium-, Natrium-, Kalium-, Rubidium- und Cäsiumsalze von Alkylendicarbonsäuren („Doppelseifen“) abgeleitet. Es wurden zwei lamellare Strukturtypen gefunden. In einer davon entspricht die Anordnung der polaren Gruppen und der Paraffinketten dem kristallisierten Zustand, in der anderen dem geschmolzenen Zustand.

Die beobachteten Strukturen wurden mit denen der einfachen Seifen (Monosäuren) mit einwertigen und zweiwertigen Metallen verglichen.

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Bibliographie

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Author notes

  1. Bernard Gallot & Antoine Skoulios

    Present address: Centre de Recherches sur les Macromolécules, Strasbourg, France

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    1. Bernard Gallot
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    2. Antoine Skoulios
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    Gallot, B., Skoulios, A. Structure des savons alcalins. Kolloid-Z.u.Z.Polymere 222, 51–55 (1968). https://doi.org/10.1007/BF01507366

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    • DOI: https://doi.org/10.1007/BF01507366

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