Abstract
The distribution coefficients of mono- and dibutyl phosphates between an organic phase containing tributyl phosphate in hydrogenated kerosene, and water and nitric acid, alkali and soda solutions were determined. It was found that a concentration of monobutyl phosphate below 0.001 mole/liter (equilibrium concentration) and of dibutyl phosphate below 0.0001 mole/liter hardly affected the extraction of plutonium with tributyl phosphate.
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Literature cited
E. M. Scadden and R. E. Ballou, Analyt. Chem. 11, 1602 (1953).
D.C. Stewart and W.C. Bently, Science 120, 50 (1954).
F.L. Culler, The Chemistry of Nuclear Fuel [Russian translation] (IL, 1956) p. 258.
F.R. Brace, Ibid., p. 321.
E.K. Hyde, Ibid., p. 393.
G.F. Best, H.A.C. McKay and P.R. Woodgate, J. Inorg. and Nucl. Chem. 4, 5/6, 315 (1957).
D.C. Stewart and H.W. Crandall, J. Amer. Chem. Soc. 73, No. 3, 1377 (1951).
B. Goldschmidt, P. Renault and I. Prevot, The Chemistry of Nuclear Fuel [Russian translation] (IL, 1956) p. 127.
H.A.C. McKay, Ibid., p. 498.
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Shevchenko, V.B., Smelov, V.S. The effect of mono- and dibutyl phosphates on the extraction of plutonium with tributyl phosphate. The Soviet Journal of Atomic Energy 5, 1455–1459 (1958). https://doi.org/10.1007/BF01498488
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DOI: https://doi.org/10.1007/BF01498488