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Viscoelastic behaviour during gelation of various molar-mass polyvinylchloride solutions and polymerization temperatures

  • Polymer Science
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Abstract

The gel formation of various 10% molar-mass polyvinyl-chloride (PVC) sample solutions and polymerization temperatures in di-(2-ethylhexyl)phthalate (DOP) was studied by measuring dynamic moduli as functions of gelation (or ageing) time and frequency. The propensity to form gels increases with increasing molar mass and decreasing polymerization temperature. Extraction of a commercial PVC with acetone separates it into a relatively highly crystalline and a nearly non-crystalline polyvinyl chloride.

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Author notes

  1. K. te Nijenhuis

    Present address: Department of Polymer Technology, Faculty of Chemical Engineering and Materials Science, Delft University of Technology, Delft, The Netherlands

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  1. DSM Research, Geleen, The Netherlands

    A. Dorrestijn

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  1. A. Dorrestijn
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  2. K. te Nijenhuis
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Dorrestijn, A., te Nijenhuis, K. Viscoelastic behaviour during gelation of various molar-mass polyvinylchloride solutions and polymerization temperatures. Colloid & Polymer Sci 268, 895–900 (1990). https://doi.org/10.1007/BF01469367

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  • DOI: https://doi.org/10.1007/BF01469367

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