Abstract
The reaction of GaH3 · NMe3 with ClPBut 2 in ether occurs through the exchange of ligands followed by reduction of Ga3+ to Gaz+ to yield (GaCl2 · NMe3)2. X-ray structural analysis demonstrated that gallium atoms in this compound form a direct metal-metal bond with the length of 2.421 Å.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 2078–2081, August, 1996.
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Pashkov, A.Y., Belsky, V.K., Butychev, M. et al. Trimethylaminedichlorogailane (Cl2Ga · NMe3)2 with the Ga-Ga intermetallic bond. Russ Chem Bull 45, 1973–1976 (1996). https://doi.org/10.1007/BF01457790
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DOI: https://doi.org/10.1007/BF01457790