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Possibility of the formation of chlorosubstituted tropone rings under Zincke-Suhl reaction conditions

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The formation of trace amounts of a chloro-substituted nonbenzoid aromatic derivative, namely, 4-methyl-5-chloro-2,4,6-cycloheptatrien-1-one under standard Zincke-Suhl reaction conditions, was detected.

  2. 2.

    The possibility was demonstrated for the formation of the product of the “anomalous Reimer-Tiemann reaction” (Auwers reaction), namely, 4-methyl-4-dichloromethyl-2,5-cyclohexadien-1-one in a Zincke-Suhl-type reaction using CHCl3 instead of the usual reagent, CCl4.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    S. V. Sergeev, V. A. Nikanorov, V. I. Rozenberg & O. A. Reutov

Authors
  1. S. V. Sergeev
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  2. V. A. Nikanorov
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  3. V. I. Rozenberg
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  4. O. A. Reutov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 911–.913, April, 1988.

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Sergeev, S.V., Nikanorov, V.A., Rozenberg, V.I. et al. Possibility of the formation of chlorosubstituted tropone rings under Zincke-Suhl reaction conditions. Russ Chem Bull 37, 790–792 (1988). https://doi.org/10.1007/BF01455507

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  • DOI: https://doi.org/10.1007/BF01455507

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