Conclusions
-
1.
Allyltriphenylarsonium iodide rearranges in the presence of diethylamine or triethylamine to give propenyltriphenylarsonium iodide. The ratio of the starting and rearranged salts is 1:3.
-
2.
Alcohols in the presence of sodium alcoholate add to propenyltriphenylarsonium iodide to form (2-alkoxypropyl)triphenylarsonium salts.
Literature cited
P. T. Keough and M. Grayson, J. Org. Chem.,29, 631 (1964).
E. E. Schweizer, J. Am. Chem. Soc.,86, 2744 (1964).
E. Zbiral, Synthesis, No. 11, 775 (1974).
D. Seyferth and J. Fogel, J. Organomet. Chem.,6, 205 (1966).
J. A. Kampmeier, S. H. Harris, and R. M. Rodenhorst, J. Am. Chem. Soc.,103, 1478 (1981).
R. Manske and J. Gosselek, Tetrahedron,31, 2121 (1975).
N. A. Nesmeyanov, V. V. Mikulshina, and O. A. Reutov, J. Organomet. Chem.,13, 263 (1968).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 908–910, April, 1988.
Rights and permissions
About this article
Cite this article
Nesmeyanov, N.A., Nikul'shina, V.V., Kharitonov, V.G. et al. Propenyltriphenylarsonium iodide and its reaction with alcohols. Russ Chem Bull 37, 787–790 (1988). https://doi.org/10.1007/BF01455506
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01455506