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Thermochemical characteristics of the formation of substituted phenoxy cations in the gas phase

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The appearance potentials were used to determine the enthalpies of formation of the p-HOC6H4,O+ (676.0) and p-NH2C6H4O+ ions (776.8 kJ/mole).

  2. 2.

    The isomerization of the molecular ions of aromatic nitro compounds to ionized nitrites requires additional energy expenditures.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 903–905, April, 1988.

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Orlov, V.M., Ponomarev, D.A., Misharev, A.D. et al. Thermochemical characteristics of the formation of substituted phenoxy cations in the gas phase. Russ Chem Bull 37, 783–784 (1988). https://doi.org/10.1007/BF01455504

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  • DOI: https://doi.org/10.1007/BF01455504

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