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Determination of the rate constant for hydrogen abstraction from propylene by CC13[CH2CH(CH3)]n] telomer radicals (n=1,2)

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The competitive kinetics method was used to show that hydrogen abstraction from propylene by telomeric CCl3[CH2CH(CH3)]n radicals (n=1, 2) proceeds at 140°C with rate constants 2.5·103 and 1.8·103 liters/mole·sec, respectively.

  2. 2.

    The polar effect upon the abstraction of hydrogen atoms from propylene by telomer radicals is less pronounced than upon the abstraction of a chlorine atom from CCl4.

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Literature cited

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    N. A. Grigor'ev & A. L. Tumanskaya

Authors
  1. N. A. Grigor'ev
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  2. A. L. Tumanskaya
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 894–897, April, 1988.

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Grigor'ev, N.A., Tumanskaya, A.L. Determination of the rate constant for hydrogen abstraction from propylene by CC13[CH2CH(CH3)]n] telomer radicals (n=1,2). Russ Chem Bull 37, 774–776 (1988). https://doi.org/10.1007/BF01455501

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  • DOI: https://doi.org/10.1007/BF01455501

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