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[2+4]-Cycloaddition of fluoroolefins and fluoroazomethines with 1,3-cyclohexadiene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Terminal fluoroolefins and internal fluoroolefins and fluoroazomethines react with 1,3-cyclohexadiene at 220–270°C to give [2+4]-cycloadducts.

  2. 2.

    Methoxycarbonyltetrafluorocrotononitrile and 1-polyfluoroalkene-1-sulfonyl fluorides react with 1,3-dicyclohexadiene at 50–80°C.

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Literature cited

  1. D. R. A. Perry, Fluor. Chem. Rev.,1, 253 (1967).

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  2. V. A. Al'bekov, V. N. Mironov, A. F. Benda, et al., Abstracts of the 5th All-Union Conference on the Chemistry of Organofluorine Compounds [in Russian], Moscow (1986), p. 3.

  3. V. A. Al'bekov, A. F. Benda, A. F. Gontar', et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1437 (1986).

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. A. Al'bekov, A. F. Benda, A. F. Gontar', G. A. Sokol'skii & I. L. Knunyants

Authors
  1. V. A. Al'bekov
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  2. A. F. Benda
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  3. A. F. Gontar'
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  4. G. A. Sokol'skii
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  5. I. L. Knunyants
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 885–890, April, 1988.

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Al'bekov, V.A., Benda, A.F., Gontar', A.F. et al. [2+4]-Cycloaddition of fluoroolefins and fluoroazomethines with 1,3-cyclohexadiene. Russ Chem Bull 37, 765–769 (1988). https://doi.org/10.1007/BF01455498

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  • DOI: https://doi.org/10.1007/BF01455498

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