Skip to main content
Log in

Kinetics of the geminal recombination of radical pairs in the photoreduction of uranyl in micelles

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The excited state of uranyl rapidly extracts an electron or hydrogen atom from amines and phenols in direct and inverted micelles.

  2. 2.

    The kinetics of the geminal recombination of the radical-ion pair containing the UO2 2+ ion in inverted micelles was measured.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Literature cited

  1. V. Balzani, F. Bolletta, M. T. Gandolfi, and M. Maestri, Topics in Current Chemistry,75, 1 (1978).

    Google Scholar 

  2. P. P. Levin and V. A. Kuz'min, Izv. Akad. Nauk SSSR, Ser. Khim., 2367 (1987).

  3. P. P. Levin and V. A. Kuz'min, Izv. Akad. Nauk SSSR, Ser. Khim., 464 (1986).

  4. G. I. Sergeeva, A. K. Chibisov, A. V. Karyakin, et al., Khim. Vysok, Énerg.,8, 30 (1974).

    Google Scholar 

  5. R. J. Hill, T. J. Kemp, D. M. Alien, and A. Cox, J. Chem. Soc., Faraday Trans, 1,70, 847 (1974).

    Google Scholar 

  6. S. J. Formosinho and M. G. M. Miguel, J. Chem. Soc., Faraday Trans, 1,81, 1891 (1985).

    Google Scholar 

  7. M. Gremtsel, in: K. Mittel (ed.), Micelle Formation, Solubilization, and Microemulsions [Russian translation], Izd. Mir, Moscow (1980), p. 269.

    Google Scholar 

  8. C. Petit, P. Biochette, and M. P. Pileni, J. Phys. Chem.,90, 6517 (1986).

    Google Scholar 

  9. P. P. Levin and V. A. Kuz'min, Dokl. Akad. Nauk SSSR,292, 134 (1987).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 880–882, April, 1988.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Levin, P.P., Kuz'min, V.A. & Khudyakov, I.V. Kinetics of the geminal recombination of radical pairs in the photoreduction of uranyl in micelles. Russ Chem Bull 37, 760–762 (1988). https://doi.org/10.1007/BF01455496

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01455496

Keywords

Navigation