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Electrochemical chlorination of ethyl acetoacetate and the formation of ethyl 2,2,4-trichloroacetoacetate

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The electrochemical chlorination of ethyl acetoacetate in aqueous media proceeds at C2 and, partially, at C4 to give ethyl 2,2-dichloroacetoacetate and small amounts of ethyl 2,2,4-trichloroacetoacetate.

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Authors and Affiliations

  1. A. N. Frumkin Institute of Electrochemistry, Academy of Sciences of the USSR, Moscow

    V. A. Ilyushin & V. G. Malaev

Authors
  1. V. A. Ilyushin
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  2. V. G. Malaev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 876–877, April, 1988.

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Ilyushin, V.A., Malaev, V.G. Electrochemical chlorination of ethyl acetoacetate and the formation of ethyl 2,2,4-trichloroacetoacetate. Russ Chem Bull 37, 756–757 (1988). https://doi.org/10.1007/BF01455494

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  • DOI: https://doi.org/10.1007/BF01455494

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