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Synthesis and reactions of organometallic carbodiimides and isocyanates

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A convenient laboratory method has been proposed for the preparation of organometallic tin and germanium carbodiimides in excellent yields and satisfactory purities.

Organotin carbodiimides react with dicarboxylic acid anhydrides to give addition products, namely, organotin derivatives of N-substituted dicarboxylic acid monocyanamides. The corresponding reaction of tin and germanium isocyanates lead to the formation of N-tributylstannyl(germyl)imides of dicarboxylic acids, and CO2.

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Authors and Affiliations

  1. Institute of Chemistry, Academy of Sciences of the USSR, Gorkii

    G. A. Razuvaev, O. S. D'yachkovskaya, I. P. Malysheva & S. E. Skobeleva

Authors
  1. G. A. Razuvaev
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  2. O. S. D'yachkovskaya
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  3. I. P. Malysheva
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  4. S. E. Skobeleva
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 859–865, April, 1988.

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Razuvaev, G.A., D'yachkovskaya, O.S., Malysheva, I.P. et al. Synthesis and reactions of organometallic carbodiimides and isocyanates. Russ Chem Bull 37, 739–744 (1988). https://doi.org/10.1007/BF01455491

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  • DOI: https://doi.org/10.1007/BF01455491

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