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Electrochemical reductive dehalogenation of halogeno-cyclopropane and halogenoaromatic compounds

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A preparative electrochemical method for the exhaustive reductive dehalogenation of gem-dichlorocyclopropanes to cyclopropanes, and of fluoro- and chloroaromatic compounds to aromatic hydrocarbons, was developed. Aqueous DMF with the 1:1 mixture of the salts Licl and MgCl2 was proposed as the electrolyte.

  2. 2.

    A method for obtaining a cathode of low deterioration, consisting of an Al support with a surface layer of Li/Mg, was described.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR

    V. A. Afanas'ev, O. N. Efimov, G. N. Nesterenko, O. M. Nefedov, A. P. Pivovarov, B. G. Rogachev & M. L. Khidekel'

  2. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. A. Afanas'ev, O. N. Efimov, G. N. Nesterenko, O. M. Nefedov, A. P. Pivovarov, B. G. Rogachev & M. L. Khidekel'

Authors
  1. V. A. Afanas'ev
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  2. O. N. Efimov
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  3. G. N. Nesterenko
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  4. O. M. Nefedov
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  5. A. P. Pivovarov
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  6. B. G. Rogachev
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  7. M. L. Khidekel'
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Additional information

For preliminary communications, see [1, 2].

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 806–809, April, 1988.

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Afanas'ev, V.A., Efimov, O.N., Nesterenko, G.N. et al. Electrochemical reductive dehalogenation of halogeno-cyclopropane and halogenoaromatic compounds. Russ Chem Bull 37, 689–692 (1988). https://doi.org/10.1007/BF01455478

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  • DOI: https://doi.org/10.1007/BF01455478

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