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Inversion of configuration in the aminolysis of N-benzenesulfonylbenzimidoyl chloride. Crystal and molecular structure of N2-benzenesulfonyl-N1-(3-nitrophenyl)benzamide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The E-molecular configuration of N2-benzenesulfonyl-N1-(3-nitrophenyl)benzamidine has been verified by x-ray structural investigation, which also made it possible to confirm the addition-elimination mechanism which had been proposed earlier for the reactions of N-aryl-sulfonylbenzimidoyl chlorides with aromatic amines in aprotic reaction media. Molecules of (II) are associated with one another in the crystal structure via H-bonds in a chain, while neighboring chains are associated with one another by means of the so-called “stacking” interactions.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organometallic Compounds, Academy of Sciences of the USSR, Moscow

    D. S. Yufit, Yu. T. Struchkov, V. A. Mikhailov, L. P. Drizhd & V. A. Savelova

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  1. D. S. Yufit
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  2. Yu. T. Struchkov
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  3. V. A. Mikhailov
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  4. L. P. Drizhd
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  5. V. A. Savelova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 783–787, April, 1988.

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Yufit, D.S., Struchkov, Y.T., Mikhailov, V.A. et al. Inversion of configuration in the aminolysis of N-benzenesulfonylbenzimidoyl chloride. Crystal and molecular structure of N2-benzenesulfonyl-N1-(3-nitrophenyl)benzamide. Russ Chem Bull 37, 667–670 (1988). https://doi.org/10.1007/BF01455473

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  • DOI: https://doi.org/10.1007/BF01455473

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