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Kinetics of overall decomposition of ozonides of 2,2′-methylene-bis-4-methyl-6-tert-butylphenyl esters of phosphorous acid

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The decomposition of ozonides of 2,2′ methylenebis-4-methyl-6-tert-butylphenyl esters of phosphorous acid esters is described by a first order equation, and the electron donor substituents decrease the stability of the ozonides.

  2. 2.

    The influence of the solvent on the rate of the overall decomposition of the ozonide of phenyl 2,2′ -methylenebis-4-methyl-6-tert-butylphenyl phosphite is described according to the Koppel'-Pal'm equation.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Branch, Academy of Sciences of the USSR, Ufa

    V. V. Sheroshovets, N. M. Korotaeva, R. K. Yanbaev, V. Kh. Kadyrova, N. A. Mukmeneva, V. D. Komissarov, G. A. Tolstikov & P. A. Kirpichnikov

  2. S. M. Kirov Kazan' Chemical Engineering Institute, USSR

    V. V. Sheroshovets, N. M. Korotaeva, R. K. Yanbaev, V. Kh. Kadyrova, N. A. Mukmeneva, V. D. Komissarov, G. A. Tolstikov & P. A. Kirpichnikov

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  1. V. V. Sheroshovets
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  2. N. M. Korotaeva
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  3. R. K. Yanbaev
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  4. V. Kh. Kadyrova
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  5. N. A. Mukmeneva
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  6. V. D. Komissarov
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  7. G. A. Tolstikov
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  8. P. A. Kirpichnikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 765–769, April, 1988.

The authors wish to express their gratitude to I. R. Akhunov for his help in carrying out the calculations.

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Sheroshovets, V.V., Korotaeva, N.M., Yanbaev, R.K. et al. Kinetics of overall decomposition of ozonides of 2,2′-methylene-bis-4-methyl-6-tert-butylphenyl esters of phosphorous acid. Russ Chem Bull 37, 650–653 (1988). https://doi.org/10.1007/BF01455468

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  • DOI: https://doi.org/10.1007/BF01455468

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