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Complexes of rhenium(V) with cyclic sulfides: Catalysts of hydrogenation and isomerization of olefins

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Complexes of rhenium with cyclic sulfur-containing ligands (thiophane, 2-propylthio-phane) catalyze hydrogenation and isomerization of olefin and diene hydrocarbons.

  2. 2.

    The catalytic activity of the complexes is a function of the ligand environment, the nature of the substrate, and the solvent.

  3. 3.

    The catalysts tested accelerate isomerization of α-olefins both in hydrogen and in an inert atmosphere with the predominant formation of cis-β-olefins.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    L. I. Gvinter, N. V. Borunova, R. G. Akhmadieva, N. V. Antseva, N. A. Yusupova, I. U. Numanov & V. Z. Sharf

  2. V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Tadzhik SSR, Dushanbe

    L. I. Gvinter, N. V. Borunova, R. G. Akhmadieva, N. V. Antseva, N. A. Yusupova, I. U. Numanov & V. Z. Sharf

Authors
  1. L. I. Gvinter
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  2. N. V. Borunova
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  3. R. G. Akhmadieva
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  4. N. V. Antseva
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  5. N. A. Yusupova
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  6. I. U. Numanov
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  7. V. Z. Sharf
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 755–759, April, 1988.

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Gvinter, L.I., Borunova, N.V., Akhmadieva, R.G. et al. Complexes of rhenium(V) with cyclic sulfides: Catalysts of hydrogenation and isomerization of olefins. Russ Chem Bull 37, 641–644 (1988). https://doi.org/10.1007/BF01455466

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  • DOI: https://doi.org/10.1007/BF01455466

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