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Temperaturabhängigkeit der parakristallinen Störungen in linearem schmelzkristallisiertem Polyäthylen 6041 D unterhalb des Schmelzpunktes

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Zusammenfassung

Die parakristallinen Gitterstörungen an linearem schmelzkristallisiertem Polyäthylen 6041D sind bei Raumtemperatur innerhalb der Meßgenauigkeit dieselben wie direkt unterhalb des Schmelzpunktes, was durch eine temperaturunabhängige Konzentration der Kinken erklärbar ist. Auffallend ist die geringe Störung der (110)-Netzebenen, für die erst genauere Messungen eine Erklärung geben können.

Summary

The paracrystalline lattice distortions of linear meltcrystallized polyethylene 6041D were measured from room temperature until just below the melting point. The paracrystalline g-values do not change within the experimental error limits. This can be explained by a temperature independent kink-con centration. The small distortion of the (110)-lattice planes is remarkable. Further measurements are needed to find an explanation.

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Authors and Affiliations

  1. Tilinstitut für Strukturforschung am Fritz-Haber-Institut der Max-Planck-Gesellschaft, 1 Berlin-Dahlem

    W. Schmidt & W. Vogel

Authors
  1. W. Schmidt
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  2. W. Vogel
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Schmidt, W., Vogel, W. Temperaturabhängigkeit der parakristallinen Störungen in linearem schmelzkristallisiertem Polyäthylen 6041 D unterhalb des Schmelzpunktes. Colloid & Polymer Sci 253, 898–902 (1975). https://doi.org/10.1007/BF01452409

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  • DOI: https://doi.org/10.1007/BF01452409

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