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Swelling equilibrium and preferential sorption of crosslinked poly(methyl methacrylate) in the mixture acetonitrile + n-butanol

  • Polymer Science
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Abstract

Measurements of preferential sorption,λ(Ν 3), determined by refractometry, and swelling equilibrium,Ν 3 −1, of PMMA networks have been carried out in the cosolvent mixture MeCN+BuOH at 25‡ and 49 ‡C. With an intermediate mixture composition,Ν 3 −1 passes through a maximum at both temperatures. At 25 ‡C MeCN is preferentially adsorbed by the network over most of the composition range, but a small inversion is detected. At 49 ‡C MeCN is preferentially adsorbed over all the composition range.

The behavior of the system crosslinked PMMA/MeCN + BuOH is compared with the results obtained for solutions of linear PMMA in mixtures formed by the same two solvents, MeCN and BuOH.

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Author notes

  1. R. M. Masegosa

    Present address: Departamento de Química Física, Facultad de Quimicas, Universitad Complutense, Madrid, Spain

Authors and Affiliations

  1. Departamento de Química Física, Facultad de Quimicas, Universitad Complutense, Madrid, Spain

    M. G. Prolongo & I. Hernández-Fuentes

  2. Departamento de Química General y Macromoléculas de Ciencias, Universidad a Distancia (UNED), Madrid, Spain

    M. A. Llorente & A. Horta

Authors
  1. R. M. Masegosa
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  2. M. A. Llorente
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  3. M. G. Prolongo
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  4. I. Hernández-Fuentes
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  5. A. Horta
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Masegosa, R.M., Llorente, M.A., Prolongo, M.G. et al. Swelling equilibrium and preferential sorption of crosslinked poly(methyl methacrylate) in the mixture acetonitrile + n-butanol. Colloid & Polymer Sci 262, 862–866 (1984). https://doi.org/10.1007/BF01452216

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  • DOI: https://doi.org/10.1007/BF01452216

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