Abstract
The kinetics of the aqueous polymerization of acrylonitrile and methyl methacrylate initiated by the peroxydiphosphate-thioglycollic acid redox system was investigated at 40, 45, 50, 55, and 60 °C. The rates of polymerization were measured at different concentrations of oxidant, activator and monomer. From the results, it was concluded that the polymerization reaction is initiated by an organic free radical arising from the peroxydiphosphate-thioglycollic acid system and termination by mutual type. On the basis of experimental observations of the dependence of the rate of polymerization,R p on various variables, a suitable kinetic scheme has been proposed.
Similar content being viewed by others
References
Lenka, S., P. L. Nayak, A. K. Dhal, Makromol. Chem., Rapid Commun.1, 313 (1980).
Nayak, P. L., S. Lenka, M. K. Mishra, J. Polym. Sci.19 (3), 839 (1981).
Lenka, S., P. L. Nayak, A. K. Dhal, Ibid.19, 211 (1981).
Lenka, S., A. K. Dhal, Ibid.. (In Press).
Lenka, S., A. K. Dhal, European Polymer Journal (In Press).
Baral, N., N. C. Pati, P. L. Nayak, S. C. Dash, Makromol. Chem., Rapid Commun. (Accepted).
Hariharan, S. S., A. Meenakshi, J. Polym. Sci.15, 1 (1977).
Riggs, J. P., F. Rodriguez, J. Polym. Sci. A 15, 3167 (1967).
Morgan, M. L., Trans. Faraday Soc.42, 140 (1946).
Guha, T., Doctoral Thesis, Calcutta University, India (1960).
Pati, N. C., S. Lenka, P. L. Nayak, T. R. Mohanty, J. Polym. Sci., Polym. Chem. Ed.16, 343 (1978).
Tudos, T., I. Kende, M. Azori, J. Polym. Sci.1, 1353 (1963).
Tudos, F., I. Kende, M. Azori, Ibidi.1, 1369 (1963).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Lenka, S., Nayak, P.L. Vinyl polymerization initiated by peroxydiphosphate. Colloid & Polymer Sci 260, 771–775 (1982). https://doi.org/10.1007/BF01452067
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF01452067