Abstract
The action of polysilicic acid on monolayers of a quaternary ammonium salt and a phospholipid spread on substrates of various pH values was studied. The films of benzyl dimethyl hexadecyl ammonium chloride were considerably affected above pH 2. No interaction was observed, at any pH, between silicic acid and dipalmitoyl phosphatidyl serine.
The results support the existence of ionic interactions between dissociated silanol groups and tetra-alkylammonium groups. The involvement of hydrogen bonds is ruled out.
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Parazzi E, Sechi GC, Pernis P, Vigliani E (1968) Arch Environ Health 17:850
Allison AC (1967) Sci Am 217:62
Allison AC (1969) In: Dingle JT, Fell HB (eds) Lysosomes and Cancer, Lysosomes in Biology and Pathology, Vol II, North Holland, Amsterdam, p 178
Scheel LD, Fleischer E, Klemperer FW (1953) Arch Ind Hyg Occup Med 8:564
Sechi GC (1967) Med Lavoro 58:412
Margolis J (1961) Aust J Exp Biol Med Sci 39:249
Summerton J, Hoenig S, Butler C, Chvapil M (1977) Exp Mol Path 26:113
Allison AC, Harington JS, Birbeck M (1966) J Exp Med 124:141
Nash T, Allison AC, Harington JS (1966) Nature 210:259
Stalder K, Stober W (1965) Nature 207:874
Holt PF, Nasrallah ET (1966) Nature 211:878
Weissman G, Rita GA (1972) Nature New Biol 240:167
Oscarson DW, Van Scoyoc GE, Ahlrichs JL (1981) J Pharm Sci 70:657
Depasse J, Warlus J (1976) J Coll Interf Sci 56:618
Depasse J (1977) J Coll Interf Sci 60:414
Theorell T, Stenhagen E (1939) Biochem Z 299:417
Miñones J, Garcia Fernández S, Iribarnegaray E, Sanz Pedrero P (1973) J Coll Interf Sci 42:503
Dervichian DG (1971) Biochim 53:25
Blois DW, Swarbrick J (1971) J Coll Interf Sci 36:226
Van Deenen LLM, Houtsmuller UMT, de Haas GH, Mulder E (1962) J Pharm Pharmacol 14:429
Miñones J, Conde O, Iribarnegaray E (1982) Acta Cientifica Compost 19(3–4):363
Pauling L (1967) The Chemical Bond, Cornell Univ Press, New-York, p 223
Allen LH, Matijević E, Meiter L (1971) J Inorg Nucl Chem 33:1293
Belkayov VN, Soltiuskii NM, Strazhesko DN, Strelko W (1974) Ukr Khim Zh, Russ Ed 40:236
Holt PF, Bowcott EL (1954) Biochem J 57:471
Abramson MB, Katzman R, Gregor HP (1964) J Biol Chem 239:70
Hauser H, Darke A, Phillips MC (1976) Eur J Biochem 62:335
Garvin JE, Karnousky ML (1956) J Biol Chem 221:211
Miñones J, Sandez Macho MI, Iribarnegaray E, Sanz Pedrero P (1981) Coll Polym Sci 259:450
Stade H, Wieker W (1971) Z. Anorg Allg Chem 384:53
Miñones J, Iribarnegaray E, García Fernández S, Sanz Pedrero P (1974) Med Segur Trab 22(88):47
Iribarnegaray E, Minones J, García Fernández S, Sanz Pedrero P (1975) Anal Quim 71:879
Roller PS, Erwing G (1940) J Amer Chem Soc 62:461
Bilinski H, Ingri N (1967) Acta Chem Scand 21:2503
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Miñones, J., Conde, O. Interaction of polysilicic acid with monolayers of substances containing quaternary ammonium groups. Colloid & Polymer Sci 266, 353–358 (1988). https://doi.org/10.1007/BF01451819
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DOI: https://doi.org/10.1007/BF01451819