Abstract
A new flow calorimeter for measuring isobaric enthalphy increment and Joule-Thomson effect was built and tested during the period 1987–1993. The calorimeter has several features that reduce the heat leakage better than previous designs; this includes thermal shields cooled by propane. a heat sink, and superinsulation on all piping. The temperature and pressure range covered by the calorimeter is 133 to 343 K and 0.17 to 14 MPa. Measurements on a mixture of 68.32% methane and 31.68% propane are presented. The enthalpy increment measurements have an average standard uncertainty of 0.08 kJ · kg−1, or 0.22% of the enthalpy increment.
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References
E. A. Manker,Thermodynamic Properties of a Methane-Propane Mixture at Low Temperature and High Pressures. Ph.D. thesis (University of Michigan, Ann Arbor, 1964).
E. A. Manker, D. T. Mage, A. E. Mather, J. E. Powers, and D. L. Katz, Enthalpy Determination on the Methane-Propane System. Proc. Ann Conv. Nat. Gas Process. Assoc. Techn. Papers, Vol. 43 (1964). pp. 3–9.
A. E. Mather, The Direct Determinationa of the Enthalpy of Fluids Under Pressure. Ph.D. thesis (University of Michigan, Ann Arbor. 1967).
A. E. Mother, J. E. Powers, and D. L. Katz. Additional Enthalpy Determination on the Methane-Propane System. Proc. Conv. Nat. Gas Process. Assoc., Techn. Papers, Vol.44 (1965). pp. 3–6.
A. E. Mather, J. E. Powers, and D. L. Katz.AlChE J. 15:111 (1969).
A. E. Mather, V. F. Yesavage, J. E. Powers, and D. L. Katz, Enthalpy Data for Binary Mixtures of Methane with Propane and with Nitrogen. Proc. Ann. Conv. Nat. Gas Process. Assoc., Techn. Papers, Vol. 45 (1966). pp. 12–19.
A. E. Mather, V. F. Yesavage, J. E. Powers, and D. L. Katz. Enthalpy Data for a Mixture of 28 Percent Propane in Methane. Proc. Conv. Nat. Gas Process. Assoc., Techn. Papers. Vol. 46 (1967). pp. 3–7.
V. F. Yesavage.The Measurement and Prediction of the Enthalpy of Fluid Alivures Under Pressure. Ph.D. thesis (University of Michigan, Ann Arbor, 1965).
V. F. Yesavage. A. W. Furtado. J. E. Powers. Results of Experimental Measurements of Enthalpy Data and Comparison with Predictions for a Mixture Containing 77 Mole Percent Propane in Methane. NGPA Rep. 47th Ann. Convent. Proc. (1965).
V. F. Yesavage. D. L. Katz. and J. E. Powers.J. Chem. Eng. Data 14(2):137 (1969).
H. Pieper.Entwicklung eines Strömungskalorimeter und Bestimmung der Spezifischen Wärmekapazitat und des Isotermen Drosseleffektes sowie Berechung der Enthalpic von N 2 , und von H 2 -C 2 H 2 , Gemischen, Dr. Ing. Thesis (Technischen Universität Berlin, 1974).
J. Mollerup,Adv. Cryogen. Eng. 23:550 (1978).
O. Jørstad.Equation of State for Hydrocarbon Mixtures, Dr. Ing. Thesis (Division of Refrigeration Engineering, Norwegian Institute of Technology. Trondheim. 1993).
B. N. Taylor and C. E. Kuyatt. NIST Technical Note 1297 (1993).
E. Brendene et al.,Measurement and Calculation of the Thermodynamic Properties of Natural Gas Mixtures (Department of Refrigeration Engineering, Norwegian Institute of Technology. Trondheim. 1993).
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Grini, P.G., Brendeng, E. & Maehlum, H.S. New enthalpy increment flow calorimeter and measurements on a mixture of 68% methane and 32% propane. Int J Thermophys 16, 167–176 (1995). https://doi.org/10.1007/BF01438967
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DOI: https://doi.org/10.1007/BF01438967