Skip to main content
Log in

Measurement of transport properties of liquids with equilibrium and nonequilibrium Rayleigh scattering

  • Published:
International Journal of Thermophysics Aims and scope Submit manuscript

Abstract

We have developed an experimental arrangement for measuring Rayleigh scattering in liquids and liquid mixtures that are either in thermal equilibrium or in thermal nonequilibrium states. As an illustrative example we report experimental values for the thermal dilfusivity, the mass diffusion coefficient, the Rayleigh-factor ratio, and the Suret coefficient of an equimolar mixture of liquid toluene andn-hexane.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. N. Shaumeyer, R. W. Gammon. J. V. Sengers, and Y. Nagasaka. inExperimental Ther- modynamics Ill. The Measurement of Transport Properties of Fluids. W. A. Wakeham, A. Nagashima, and J. V. Sengers, eds. (Blackwell Scientific, Oxford, 1991), p. 195.

    Google Scholar 

  2. P. N. Segrè, R. W. Gammon. J. V. Sengers, and B. W. Law,Phys. Rev. A 45:714 (1992).

    Google Scholar 

  3. P. N. Segrè, R. W. Gammon. and J. V. Sengers,Phys. Rev. E 47:1026 (1993).

    Google Scholar 

  4. B. M. Law and J. C. Nieuwoudt,Phys. Rev. A 40:3880 (1989).

    Google Scholar 

  5. W. B. Li. P. N. Segré. J. V. Sengers, and R. W. Gammon.Physica A 204:399 (1994).

    Google Scholar 

  6. A. Leipertz,Int. J. Thermophys. 9:897 (1988).

    Google Scholar 

  7. H. J. V. Tyrell,Diffusion and Heat Flow in Liquid (Butterworths, London, 1961 ). CHap. 9.

    Google Scholar 

  8. J. R. Dorfman, T. R. Kirkpatrick, and J. V. Sengers.Annu. Rev. Phys. Chem. 45:213 (1994).

    Google Scholar 

  9. P. N. Segrè and J. V. Sengers,Physica A 198:46 (1993).

    Google Scholar 

  10. M. Born and E. Wolf,Principle of Optics (Pergamon, Oxford, 1965). Chap. 7.

    Google Scholar 

  11. K. Schätzel, inOptical Measurements in Fluid Mechanics 1985. Inst. Phys. Conf. Ser. No. 77, P. H. Richards. ed. (Adam Hilger, Bristol. 1985), p. 175.

    Google Scholar 

  12. R. K. Ghai and F. A. L. Dullien.J. Phys. Chem. 78:2283 (1974).

    Google Scholar 

  13. W. B. Li. P. N. Segrè, R. W. Gammon, J. V. Sengers, and M. Lamvik,J. Chem. Phys. 101:5058 (1994).

    Google Scholar 

  14. D. W. Scott. G. B. Guthrie. J. F. Messerly S. S. Todd. W. T. Berg, I. A. Hossenlopp and J. P. McCulloughJ. Phys. Chem. 66:911 (1963).

    Google Scholar 

  15. R. Thaw.J. Chem. Eng. Data 14:461 (1969).

    Google Scholar 

  16. H. Kashiwagi. M. Oishi, Y. Tangka, H. Kubota, and T. Makita.Int. J. Thermophys. 3:101 (1982).

    Google Scholar 

  17. N. V. Tsederberg,Thermal Comhectivity of Gases and Liquids: (MIT Press. Cambridge. MA. 1965), p. 212.

    Google Scholar 

  18. O. Ecenarro, J. A. Madariaga, J. Navarro, C. M. Santamaria. J. A. Carrió, and J. M. Saviró.J. Phys. Condens. Matter 2:2289 (1990).

    Google Scholar 

  19. O. Ecenarro. personal communication (1994).

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Li, W.B., Sengers, J.V., Gammon, R.W. et al. Measurement of transport properties of liquids with equilibrium and nonequilibrium Rayleigh scattering. Int J Thermophys 16, 23–31 (1995). https://doi.org/10.1007/BF01438954

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01438954

Key words

Navigation