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Correlation and prediction of dense fluid transport coefficients. VII. Refrigerants

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Abstract

A recently developed scheme, based on considerations of hard-sphere theory, is used for the simultaneous correlation of the coefficients of viscosity and thermal conductivity for the refrigerants R11, R12, R22, R32. R124, R125, R134a, R141b, and R152a in excellent agreement with experiment, over extended temperature and pressure ranges. Values for the roughness factors and correlations for the characteristic volume are presented. The overall average absolute deviations of the experimental viscosity and thermal conductivity measurements from those calculated by the correlation are 2.1 and 2.3%, respectively, over a temperature range from 200 to about 10 K below the critical temperature and a pressure range from saturation to about 40 MPa. Since the proposed scheme is based on recent and accurate density values, a Tail-type equation was also employed to correlate successfully the density of the refrigerants. The overall average absolute deviation of the experimental density measurements from those calculated by the correlation is ±0.08%.

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Authors and Affiliations

  1. Faculty of Chemical Engineering, Aristotle University, 54006, Thessaloniki, Greece

    M. J. Assael & S. K. Polimatidou

  2. Chemistry Department, University of Glasgow, G12 8QQ, Glasgow, United Kingdom

    J. H. Dymond

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  1. M. J. Assael
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  2. J. H. Dymond
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  3. S. K. Polimatidou
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Assael, M.J., Dymond, J.H. & Polimatidou, S.K. Correlation and prediction of dense fluid transport coefficients. VII. Refrigerants. Int J Thermophys 16, 761–772 (1995). https://doi.org/10.1007/BF01438861

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