Abstract
We have used a microscopic theory to study the size dependence of the degree of localization of the valence electrons and holes in neutral an ionized rare-gas-and Hg n clusters. We discuss under which circumstances localization of the electrons and holes is favoured. We have calculated the ionization potential of Xe n , Kr n and small Hg n clusters. Good agreement with experiments is obtained. We have also determined the dependence of the ionization potential on cluster structure.
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This paper was originally submitted in connection with the 2nd. Int. Conference on Atomic and Nuclear Clusters held in Santorini from 28. June–2. July 1993 and is published here as a regular article after an independent refereeing procedure according to the standards of Z. Phys. D
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Garcia, M.E., Bennemann, K.H. On the localization of electrons and holes in Hg n and rare-gas clusters. Z Phys D - Atoms, Molecules and Clusters 31, 205–207 (1994). https://doi.org/10.1007/BF01437837
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DOI: https://doi.org/10.1007/BF01437837