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LIF measurement of the vibrational dependence of the N2(B 3Π g ) hyperfine splitting parameters

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Zeitschrift für Physik D Atoms, Molecules and Clusters

Abstract

From very high resolution (8 MHz FWHM) LIF measurements, the hyperfine coupling constants of N2(A 3Σ + u ) and N2(B 3Π g ) have been obtained for three pairs of vibrational quantum numbersv′,v″. TheA-state constants are in very good agreement with accurate literature data. The vibrational dependence of some of theB-state constants is found to be much more pronounced. This is qualitatively explained in terms of the electronic structure of the two states.

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Author notes

  1. D. Neuschäfer

    Present address: CIBA-GEIGY, CH-4002, Basel, Switzerland

Authors and Affiliations

  1. Max-Planck-Institut für Strömungsforschung, Postfach 2853, D-3400, Göttingen, Federal Republic of Germany

    H. Geisen, D. Neuschäfer & Ch. Ottinger

Authors
  1. H. Geisen
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  2. D. Neuschäfer
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  3. Ch. Ottinger
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Geisen, H., Neuschäfer, D. & Ottinger, C. LIF measurement of the vibrational dependence of the N2(B 3Π g ) hyperfine splitting parameters. Z Phys D - Atoms, Molecules and Clusters 17, 137–144 (1990). https://doi.org/10.1007/BF01437669

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  • DOI: https://doi.org/10.1007/BF01437669

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